^C. J. Howard, J. C. Taylor and A. B. Waugh. Crystallographic parameters in α-UF5 and U2F9 by multiphase refinement of high-resolution neutron powder data. Journal of Solid State Chemistry. 1982, 45: 396–398. doi:10.1016/0022-4596(82)90185-2.
^ 2.02.12.2Georg Brauer (Hrsg.), unter Mitarbeit von Marianne Baudler u. a.: Handbuch der Präparativen Anorganischen Chemie. 3., umgearbeitete Auflage. Band II, Ferdinand Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1203–1204.
^Gordon W. Halstead, P. Gary Eller "Uranium(V) Fluorides and Alkoxides" Inorganic Syntheses 1982, volume 21, 162. doi:10.1002/9780470132524.ch35
^P. G. Eller, A. C. Larson, J. R. Peterson, D. D. Ensor, J. P. Young: „Crystal structures of α-UF5 and U2F9 and spectral characterization of U2F9“, in: Inorganica Chimica Acta, 1979, 37 (2), S. 129–133 (doi:10.1016/S0020-1693(00)95530-0 ).
^Eller, P. G.; Larson, A. C.; Peterson, J. R.; Ensor, D. D.; Young, J. P. Crystal Structures of α-UF5 and U2F9 and Spectral Characterization of U2F9. Inorganica Chimica Acta. 1979, 37 (2): 129–133. doi:10.1016/S0020-1693(00)95530-0.
^ 6.06.1Howard, C. J.; Taylor, J. C.; Waugh, A. B. Crystallographic Parameters in α-UF5 and U2F9 by Multiphase Refinement of High-Resolution Neutron Powder Data. Journal of Solid State Chemistry. 1982, 45 (3): 396–398. Bibcode:1982JSSCh..45..396H. doi:10.1016/0022-4596(82)90185-2.
^Taylor, J. C.; Waugh, A. B. Neutron Diffraction Study of β-Uranium Pentafluoride Between 77 and 403 K. Journal of Solid State Chemistry. 1980, 35 (2): 137–147. Bibcode:1980JSSCh..35..137T. doi:10.1016/0022-4596(80)90485-5.
十月 19, 2023
五氟化铀, 是一种铀的氟化物, 其化学式为uf5, 识别cas号, 13775, chemspider, 14676182smiles, finchi, 5inchikey, ykldbriijyaxgs, aacrgikgaa性质化学式, uf5摩尔质量, 020926, 若非注明, 所有数据均出自标准状态, 是一种配位聚合物, 由uf5单元通过氟桥键连接成线形链, 这种铀盐的特点已经由c, howard, taylor和a, waugh报道, 制备, 编辑是把四氟化铀氟化成, uf6时的中间体, uf6它也可以. 五氟化铀是一种铀的氟化物 其化学式为UF5 五氟化铀识别CAS号 13775 07 0 ChemSpider 14676182SMILES F U F F F FInChI 1 5FH U h5 1H q 2 p 5InChIKey YKLDBRIIJYAXGS AACRGIKGAA性质化学式 UF5摩尔质量 333 020926 g mol 若非注明 所有数据均出自标准状态 25 100 kPa 下 五氟化铀是一种配位聚合物 由UF5单元通过氟桥键连接成线形链 这种铀盐的特点已经由C J Howard J C Taylor和A B Waugh报道 1 制备 编辑五氟化铀是把四氟化铀氟化成 UF6时的中间体 2 UF4 F2 2 UF5 2 UF5 F2 2 UF6它也可以由六氯化铀或五氯化铀和氟化氢反应而成 2 2 U C l 6 10 H F 2 U F 5 10 H C l C l 2 displaystyle mathrm 2 UCl 6 10 HF longrightarrow 2 UF 5 10 HCl Cl 2 nbsp 2 U C l 5 10 H F 2 U F 5 10 H C l displaystyle mathrm 2 UCl 5 10 HF longrightarrow 2 UF 5 10 HCl nbsp 五氟化铀还可以通过六氟化铀和四氟化铀的归中反应而成 2 U F 4 U F 6 2 U F 5 displaystyle mathrm UF 4 UF 6 longrightarrow 2 UF 5 nbsp 它也可以由六氟化铀被一氧化碳在高温下还原而成 3 2 UF6 CO 2 UF5 COF2使用其它还原剂 例如溴化氢 2 和二氧化硫 4 也是可行的 5 结构 编辑a相的五氟化铀是一种多聚体 由U F U顺式桥连和UF6八面体相连而成的无限链状结构 6 这个结构和五氟化钒一样 b相的五氟化铀中的铀中心是四方反棱柱结构的 7 b相会在 130 C时转化成a相 6 参考资料 编辑 C J Howard J C Taylor and A B Waugh Crystallographic parameters in a UF5 and U2F9 by multiphase refinement of high resolution neutron powder data Journal of Solid State Chemistry 1982 45 396 398 doi 10 1016 0022 4596 82 90185 2 2 0 2 1 2 2 Georg Brauer Hrsg unter Mitarbeit von Marianne Baudler u a Handbuch der Praparativen Anorganischen Chemie 3 umgearbeitete Auflage Band II Ferdinand Enke Stuttgart 1978 ISBN 3 432 87813 3 S 1203 1204 Gordon W Halstead P Gary Eller Uranium V Fluorides and Alkoxides Inorganic Syntheses 1982 volume 21 162 doi 10 1002 9780470132524 ch35 P G Eller A C Larson J R Peterson D D Ensor J P Young Crystal structures of a UF5 and U2F9 and spectral characterization of U2F9 in Inorganica Chimica Acta 1979 37 2 S 129 133 doi 10 1016 S0020 1693 00 95530 0 Eller P G Larson A C Peterson J R Ensor D D Young J P Crystal Structures of a UF5 and U2F9 and Spectral Characterization of U2F9 Inorganica Chimica Acta 1979 37 2 129 133 doi 10 1016 S0020 1693 00 95530 0 6 0 6 1 Howard C J Taylor J C Waugh A B Crystallographic Parameters in a UF5 and U2F9 by Multiphase Refinement of High Resolution Neutron Powder Data Journal of Solid State Chemistry 1982 45 3 396 398 Bibcode 1982JSSCh 45 396H doi 10 1016 0022 4596 82 90185 2 Taylor J C Waugh A B Neutron Diffraction Study of b Uranium Pentafluoride Between 77 and 403 K Journal of Solid State Chemistry 1980 35 2 137 147 Bibcode 1980JSSCh 35 137T doi 10 1016 0022 4596 80 90485 5 取自 https zh wikipedia org w index php title 五氟化铀 amp oldid 72042208, 维基百科,wiki,书籍,书籍,图书馆,