氟试剂（英语：Selectfluor），又名1-氯甲基-4-氟-1,4-氮鎓双环[2.2.2]辛烷双(四氟硼酸盐)，是Air Products and Chemicals公司的商品名，在化学中用作氟供体试剂。它是杂环化合物DABCO的衍生物。它最初于1992年被报道，为无色固体。[2]它在有机氟化学中用作亲电氟化试剂。
^Banks, R. Eric; Murtagh, Vincent; An, Ilhwan; Maleczka, Robert E. 1-(Chloromethyl)-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane Bis(tetrafluoroborate). Encyclopedia of Reagents for Organic Synthesis. 2007. ISBN 978-0471936237. doi:10.1002/047084289X.rc116.pub2.
^ 2.02.1Banks, R. Eric; Mohialdin-Khaffaf, Suad N.; Lal, G. Sankar; Sharif, Iqbal; Syvret, Robert G. 1-Alkyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts: a novel family of electrophilic fluorinating agents. Journal of the Chemical Society, Chemical Communications. 1992, (8): 595. doi:10.1039/C39920000595.
拓展阅读
Lal, G. S., J. Org. Chem. 1993, 58, 2791.
Lal, G. S., Synth. Commun. 1995, 25 (5), 725.
Banks, R. E.; Lawrence, N. J.; Popplewell, A. L., J. Chem. Soc., Chem. Commun. 1994, 343.
Banks, R. E., J. Fluorine Chem. 1998, 87, 1.
Zupan, M.; Iskra, J.; Stavber, S., J. Fluorine Chem., 1995, 70, 7.
Matthews, D.P.; Miller, S. C.; Jarvi E. T.; Sabol, J. S.; McCarthy, J. R., Tettrahedron Lett. 1993, 34 (19), 3057.
Brunaus, M.; Dell, C. P.; Owton, W. M., J. Fluorine Chem. 1994, 201.
McClinton, M. A. ; Sik, V., J. Chem. Soc., Perkin Trans. I, 1992, 1891.
Hodson, H. F.; Madge, D. J.; Slawin, A. N. Z.; Widdawson, D. A.; Williams, D. J., Tetrahedron, 1994, 50 (6), 1899.
Stavber, S.; Zupan, M., J. Chem. Soc., Chem. Commun. 1994, 149.
Stavber, S.; Sotler, J.; Zupan, M., Tettrahedron Lett. 1994, 35 (7), 1105.
专利文献
US 5459267 "1-substituted-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane salts and their application as fluorinating agents"
US 55227493 "Fluorinated Sulfonamide Derivatives"
US 5086178 "Fluorinated Diazabicycloalkane Derivatives"
US 5473065 "Fluorinated Diazabicycloalkane Derivatives"
US 5442084 "Method of Selective Fluorination"
行進 31, 2023
氟试剂, 英语, selectfluor, 又名1, 氯甲基, 氮鎓双环, 辛烷双, 四氟硼酸盐, 是air, products, chemicals公司的商品名, 在化学中用作氟供体试剂, 它是杂环化合物dabco的衍生物, 它最初于1992年被报道, 为无色固体, 它在有机氟化学中用作亲电氟化试剂, iupac名1, chloromethyl, fluoro, diazonia, bicyclo, octane, ditetrafluoroborate别名, teda1, 氯甲基, 氮𬭩双环, 辛烷双, 四氟硼. 氟试剂 英语 Selectfluor 又名1 氯甲基 4 氟 1 4 氮鎓双环 2 2 2 辛烷双 四氟硼酸盐 是Air Products and Chemicals公司的商品名 在化学中用作氟供体试剂 它是杂环化合物DABCO的衍生物 它最初于1992年被报道 为无色固体 2 它在有机氟化学中用作亲电氟化试剂 氟试剂IUPAC名1 chloromethyl 4 fluoro 1 4 diazonia wbr bicyclo 2 2 2 octane ditetrafluoroborate别名 F TEDA1 氯甲基 4 氟 1 4 氮𬭩双环 2 2 2 辛烷双 四氟硼酸盐 氟化剂识别CAS号 140681 55 6 PubChem 2724933ChemSpider 2007047SMILES B F F F F B F F F F C1C N 2 CC N 1 CC2 CCl FInChI 1 C7H14ClFN2 2BF4 c8 7 10 1 4 11 9 5 2 10 6 3 10 2 2 1 3 4 5 h1 7H2 q 2 2 1InChIKey TXRPHPUGYLSHCX UHFFFAOYAIEINECS 414 380 4性质化学式 C7H14B2ClF9N2摩尔质量 354 26 g mol 外观 无色固体熔点 190 C 463 K gt 80 C时开始分解 实际熔点不明 1 若非注明 所有数据均出自标准状态 25 100 kPa 下 目录 1 制备 2 参考文献 2 1 拓展阅读 2 2 专利文献制备 编辑氟试剂可由下列方法制备 2 参考文献 编辑 Banks R Eric Murtagh Vincent An Ilhwan Maleczka Robert E 1 Chloromethyl 4 fluoro 1 4 diazoniabicyclo 2 2 2 octane Bis tetrafluoroborate Encyclopedia of Reagents for Organic Synthesis 2007 ISBN 978 0471936237 doi 10 1002 047084289X rc116 pub2 2 0 2 1 Banks R Eric Mohialdin Khaffaf Suad N Lal G Sankar Sharif Iqbal Syvret Robert G 1 Alkyl 4 fluoro 1 4 diazoniabicyclo 2 2 2 octane salts a novel family of electrophilic fluorinating agents Journal of the Chemical Society Chemical Communications 1992 8 595 doi 10 1039 C39920000595 拓展阅读 编辑 Lal G S J Org Chem 1993 58 2791 Lal G S Synth Commun 1995 25 5 725 Banks R E Lawrence N J Popplewell A L J Chem Soc Chem Commun 1994 343 Banks R E J Fluorine Chem 1998 87 1 Zupan M Iskra J Stavber S J Fluorine Chem 1995 70 7 Matthews D P Miller S C Jarvi E T Sabol J S McCarthy J R Tettrahedron Lett 1993 34 19 3057 Brunaus M Dell C P Owton W M J Fluorine Chem 1994 201 McClinton M A Sik V J Chem Soc Perkin Trans I 1992 1891 Hodson H F Madge D J Slawin A N Z Widdawson D A Williams D J Tetrahedron 1994 50 6 1899 Stavber S Zupan M J Chem Soc Chem Commun 1994 149 Stavber S Sotler J Zupan M Tettrahedron Lett 1994 35 7 1105 专利文献 编辑 US 5459267 1 substituted 4 fluoro 1 4 diazoniabicyclo 2 2 2 octane salts and their application as fluorinating agents US 55227493 Fluorinated Sulfonamide Derivatives US 5086178 Fluorinated Diazabicycloalkane Derivatives US 5473065 Fluorinated Diazabicycloalkane Derivatives US 5442084 Method of Selective Fluorination 取自 https zh wikipedia org w index php title 氟试剂 amp oldid 75197118, 维基百科，wiki，书籍，书籍，图书馆，
