^ 1.01.11.2Perry, Dale L.; Phillips, Sidney L. Handbook of inorganic compounds. Boca Raton: CRC Press. 1995: 428. ISBN 0-8493-8671-3. OCLC 32347397.
^ 2.02.12.2Haynes, William M.; Lide, David R.; Bruno, Thomas J. CRC handbook of chemistry and physics : a ready-reference book of chemical and physical data.. Boca Raton, Florida. 2017: 104. ISBN 978-1-4987-5429-3. OCLC 957751024.
^ 3.03.13.23.3Lassner, Erik; Schubert, Wolf-Dieter. Tungsten : Properties, Chemistry, Technology of the Element, Alloys, and Chemical Compounds. Boston, MA. 1999: 168. ISBN 1-4615-4907-8. OCLC 1113605323.
^ 5.05.1Mendicino, L.; Electrochemical Society. Dielectric Science and Technology Division; Electrochemical Society. Meeting; Symposium on Environmental Issues with Materials and Processes in the Electronics and Semiconductor Industries. Environmental issues with materials and processes for the electronics and semiconductor industries : proceedings of the fourth international symposium. Pennington, NJ: Electrochemical Society. 2001: 180. ISBN 1-56677-312-1. OCLC 48710248.
^Lippard, Stephen J. Progress in inorganic chemistry. Volume 28. New York, N.Y.: Wiley. 1981: 245. ISBN 978-0-470-16679-6. OCLC 123541241.
^Johnson, B. F. G. Inorganic chemistry of the transition elements. Volume 4, A review of the literature published between October 1973 and September 1974. London: Chemical Society. 1976: 138. ISBN 978-1-84755-645-5. OCLC 820579758.
^Levason, William; Reid, Gillian; Zhang, Wenjian. Coordination complexes of the tungsten(VI) oxide fluorides WOF4 and WO2F2 with neutral oxygen- and nitrogen-donor ligands. Journal of Fluorine Chemistry (Elsevier BV). 2016, 184: 50–57. ISSN 0022-1139. doi:10.1016/j.jfluchem.2016.02.003.
^Arnaudet, Lucile; Bougon, Roland; Charpin, Pierrette; Isabey, Jacques; Lance, Monique; Nierlich, Martine; Vigner, Julien. Preparation, characterization, and crystal structure of the adducts WOF4.nC5H5N (n = 1, 2). Inorganic Chemistry (American Chemical Society (ACS)). 1989, 28 (2): 257–262. ISSN 0020-1669. doi:10.1021/ic00301a020.
十月 06, 2023
四氟氧化钨, 是一种无机化合物, 化学式为wof4, 易水解, 其反应活性类似于六氟化钨, 识别cas号, 13520, pubchem, 139487smiles, finchi, 性质化学式, wof4摩尔质量, 外观, 无色晶体, 密度, 熔点, 沸点, 溶解性, 反应, 溶解性, 可溶于氯仿, 微溶于二硫化碳, 结构晶体结构, 单斜晶系危险性欧盟分类, 未列出相关物质其他阴离子, 四氯氧化钨四溴氧化钨其他阳离子, 四氟氧化钼相关化学品, 二氟二氧化钨若非注明, 所有数据均出自标准状态, 制备, 编辑wof4. 四氟氧化钨是一种无机化合物 化学式为WOF4 易水解 其反应活性类似于六氟化钨 4 四氟氧化钨识别CAS号 13520 79 1 PubChem 139487SMILES O W F F F FInChI 1S 4FH O W h4 1H 性质化学式 WOF4摩尔质量 275 83 g mol 外观 无色晶体 1 密度 5 07 g cm3 2 熔点 110 C 383 K 2 沸点 185 C 458 K 溶解性 水 反应 2 溶解性 可溶于氯仿 3 微溶于二硫化碳 3 结构晶体结构 单斜晶系危险性欧盟分类 未列出相关物质其他阴离子 四氯氧化钨四溴氧化钨其他阳离子 四氟氧化钼相关化学品 二氟二氧化钨若非注明 所有数据均出自标准状态 25 100 kPa 下 制备 编辑WOF4可由氟气于230 400 和三氧化钨反应得到 4 WO3 2 F2 WOF4 2 O2它也可以由钨和氧气和氟气的混合物在高温下反应而成 1 六氟化钨的部分水解也能产生WOF4 5 WF 6 H 2 O WOF 4 2 HF displaystyle ce WF6 H2O gt WOF4 2 HF nbsp 四氯氧化钨和氟化氢的反应也会产生WOF4 3 WOCl 4 4 HF WOF 4 4 HCl displaystyle ce WOCl4 4HF gt WOF4 4HCl nbsp WOF4还可以由氟化铅和三氧化钨在700 C下反应而成 3 2 PbF 2 WO 3 WOF 4 2 PbO displaystyle ce 2PbF2 WO3 gt WOF4 2PbO nbsp 性质 编辑四氟氧化钨是无色固体 会水解成钨酸 1 5 WOF 4 2 H 2 O WO 3 4 HF displaystyle ce WOF4 2 H2O gt WO3 4 HF nbsp 固态的WOF4之前假定为四聚体结构 6 后来受到光谱学研究的质疑 在气态下 该分子具有单体结构 7 四氟氧化钨可以和乙腈等配体形成配合物 8 9 参考文献 编辑 1 0 1 1 1 2 Perry Dale L Phillips Sidney L Handbook of inorganic compounds Boca Raton CRC Press 1995 428 ISBN 0 8493 8671 3 OCLC 32347397 2 0 2 1 2 2 Haynes William M Lide David R Bruno Thomas J CRC handbook of chemistry and physics a ready reference book of chemical and physical data Boca Raton Florida 2017 104 ISBN 978 1 4987 5429 3 OCLC 957751024 3 0 3 1 3 2 3 3 Lassner Erik Schubert Wolf Dieter Tungsten Properties Chemistry Technology of the Element Alloys and Chemical Compounds Boston MA 1999 168 ISBN 1 4615 4907 8 OCLC 1113605323 4 0 4 1 朱文祥 无机化合物制备手册 化学工业出版社 2006 pp 269 132 四氟氧钨 ISBN 7 5025 8537 0 5 0 5 1 Mendicino L Electrochemical Society Dielectric Science and Technology Division Electrochemical Society Meeting Symposium on Environmental Issues with Materials and Processes in the Electronics and Semiconductor Industries Environmental issues with materials and processes for the electronics and semiconductor industries proceedings of the fourth international symposium Pennington NJ Electrochemical Society 2001 180 ISBN 1 56677 312 1 OCLC 48710248 Lippard Stephen J Progress in inorganic chemistry Volume 28 New York N Y Wiley 1981 245 ISBN 978 0 470 16679 6 OCLC 123541241 Johnson B F G Inorganic chemistry of the transition elements Volume 4 A review of the literature published between October 1973 and September 1974 London Chemical Society 1976 138 ISBN 978 1 84755 645 5 OCLC 820579758 Levason William Reid Gillian Zhang Wenjian Coordination complexes of the tungsten VI oxide fluorides WOF4 and WO2F2 with neutral oxygen and nitrogen donor ligands Journal of Fluorine Chemistry Elsevier BV 2016 184 50 57 ISSN 0022 1139 doi 10 1016 j jfluchem 2016 02 003 Arnaudet Lucile Bougon Roland Charpin Pierrette Isabey Jacques Lance Monique Nierlich Martine Vigner Julien Preparation characterization and crystal structure of the adducts WOF4 nC5H5N n 1 2 Inorganic Chemistry American Chemical Society ACS 1989 28 2 257 262 ISSN 0020 1669 doi 10 1021 ic00301a020 取自 https zh wikipedia org w index php title 四氟氧化钨 amp oldid 73999266, 维基百科，wiki，书籍，书籍，图书馆，
