^Dyson, P.; Hammick, D. L. 362. Experiments on the mechanism of decarboxylation. Part I. Decomposition of quinaldinic and isoquinaldinic acids in the presence of compounds containing carbonyl groups. J. Chem. Soc. 1937: 1724. doi:10.1039/jr9370001724.
^Hammick, D. L.; Dyson, P. 172. The mechanism of decarboxylation. Part II. The production of cyanide-like ions from α-picolinic, quinaldinic, and isoquinaldinic acids. J. Chem. Soc. 1939: 809. doi:10.1039/jr9390000809.
^Brown, E. V.; Shambhu, M. B. Hammick reaction of methoxypyridine-2-carboxylic acids with benzaldehyde. Preparation of methoxy-2-pyridyl phenyl ketones. J. Org. Chem. 1971, 36: 2002. doi:10.1021/jo00813a034.
^Sperber, N.; Papa, D.; Schwenk, E.; Sherlock, M. Pyridyl-Substituted Alkamine Ethers as Antihistaminic Agents. J. Am. Chem. Soc. 1949, 71: 887. doi:10.1021/ja01171a034.
一月 31, 2024
哈米克反应, 英語, hammick, reaction, 得名於英国化学家达尔齐尔, 哈米克, 指在羰基化合物存在下, 吡啶甲酸及其类似物受热转变为2, 吡啶基原醇, 用对异丙基甲苯作溶剂可提高反应产率, 反应机理, 编辑加热时, 吡啶甲酸发生脱羧, 生成两性离子, 该离子与强亲电试剂, 如醛, 作用, 发生对羰基的亲核加成, 加成产物发生质子转移, 便得到原醇, nbsp, 的机理参见, 编辑化学反应列表参考资料, 编辑, dyson, hammick, experiments, mechanism, deca. 哈米克反应 英語 Hammick reaction 得名於英国化学家达尔齐尔 哈米克 指在羰基化合物存在下 a 吡啶甲酸及其类似物受热转变为2 吡啶基原醇 1 2 3 哈米克反应用对异丙基甲苯作溶剂可提高反应产率 4 反应机理 编辑加热时 a 吡啶甲酸发生脱羧 生成两性离子 2 该离子与强亲电试剂 如醛 作用 发生对羰基的亲核加成 加成产物发生质子转移 便得到原醇 4 nbsp 哈米克反应的机理参见 编辑化学反应列表参考资料 编辑 Dyson P Hammick D L 362 Experiments on the mechanism of decarboxylation Part I Decomposition of quinaldinic and isoquinaldinic acids in the presence of compounds containing carbonyl groups J Chem Soc 1937 1724 doi 10 1039 jr9370001724 Hammick D L Dyson P 172 The mechanism of decarboxylation Part II The production of cyanide like ions from a picolinic quinaldinic and isoquinaldinic acids J Chem Soc 1939 809 doi 10 1039 jr9390000809 Brown E V Shambhu M B Hammick reaction of methoxypyridine 2 carboxylic acids with benzaldehyde Preparation of methoxy 2 pyridyl phenyl ketones J Org Chem 1971 36 2002 doi 10 1021 jo00813a034 Sperber N Papa D Schwenk E Sherlock M Pyridyl Substituted Alkamine Ethers as Antihistaminic Agents J Am Chem Soc 1949 71 887 doi 10 1021 ja01171a034 取自 https zh wikipedia org w index php title 哈米克反应 amp oldid 77134798, 维基百科,wiki,书籍,书籍,图书馆,