维基百科
天麻苷元
天麻苷元（英語：Gastrodigenin，或称为4-羟基苯甲醇，或对羟基苯甲醇）是一种苯酚衍生物，是天麻素（Gastrodin）的糖苷配基[3]，存在于天麻（学名：Gastrodia elata）等植物中[4]。它可由4-羟基苯甲醛被硼氢化钠（或氢气[5]）还原得到。[6]
| Gastrodigenin | |
|---|---|
| IUPAC名 4-(Hydroxymethyl)phenol | |
| 别名 | 4-Hydroxybenzyl alcohol |
| 识别 | |
| CAS号 | 623-05-2 |
| PubChem | 125 |
| ChemSpider | 122 |
| SMILES |
|
| InChI |
|
| InChIKey | BVJSUAQZOZWCKN-UHFFFAOYAV |
| 性质 | |
| 化学式 | C7H8O2 |
| 摩尔质量 | 124.14 g·mol−1 |
| 熔点 | 124.5 °C（397.6 K）[1] |
| 沸点 | 252 °C（525 K）[1] |
| 溶解性（水） | 6.6 g（25 °C）[2] |
| 若非注明，所有数据均出自一般条件（25 ℃，100 kPa）下。 | |
参考文献
- ^ 1.0 1.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFindern. [2021-02-01].
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 ((C) 1994-2021 ACD/Labs). Retrieved from SciFindern. [2021-02-01].
- ^ Guo, Z.; Tan, T.; Zhong, Y.; Wu, C. Study of the mechanism of gastrodin and derivatives of gastrodigenin [Study of the mechanism of gastrodin and derivatives of gastrodigenin]. Hua Xi Yi Ke da Xue Xue Bao / Journal of West China University of Medical Sciences. 1991, 22 (1): 79–82. PMID 1663484 （中文）.
- ^ Hayashi, J.; Sekine, T.; Deguchi, S.; Lin, Q.; Horie, S.; Tsuchiya, S.; Yano, S.; Watanabe, K.; Ikegami, F. Phenolic compounds from Gastrodia rhizome and relaxant effects of related compounds on isolated smooth muscle preparation. Phytochemistry. 2002, 59 (5): 513–519. PMID 11853746. doi:10.1016/S0031-9422(02)00008-0.
- ^ Yanan Wang, Youquan Deng, Feng Shi. Active palladium catalyst preparation for hydrogenation reactions of nitrobenzene, olefin and aldehyde derivatives. Journal of Molecular Catalysis A: Chemical. 2014-12, 395: 195–201 [2021-02-01]. doi:10.1016/j.molcata.2014.08.026. （原始内容于2018-06-17） （英语）.
- ^ Naimi-Jamal, M. R.; Mokhtari, J.; Dekamin, Mohammad G. Fast and efficient method for quantitative reduction of carbonyl compounds by NaBH4 under solvent-free conditions. Proceedings of the International Electronic Conference on Synthetic Organic Chemistry, 11th, Nov. 1-30, 2007. 017/1-a017/5. ISBN 3-906980-19-7.