^Smith, Michael B.; March, Jerry, Advanced Organic Chemistry: Reactions, Mechanisms, and Structure 6th, New York: Wiley-Interscience, 2007, ISBN 978-0-471-72091-1
^Shinichi Yamabe; Guixiang Zeng; Wei Guan; Shigeyoshi Sakaki. Proton transfers in the Strecker reaction revealed by DFT calculations. Beilstein Journal of Organic Chemistry. 2014, 10: 1765–1774. PMC 4143099. PMID 25161735. doi:10.3762/bjoc.10.184.
^Liebig, Justus (1835) "Ueber die Producte der Oxydation des Alkohols" (On the products of oxidation of alcohol [i.e., ethanol]), Annalen der Chemie, 14 : 133–167. In 1821, Döbereiner had prepared what he called Saüerstoffäther (literally: ether oxide), which, as Liebig later showed, contained acetaldehyde. On p. 134, Liebig states that Döbereiner first produced 1-amino-ethanol by perfusing acetaldehyde (Saüerstoffäther or Aldehyd, as Liebig called it) with ammonia gas (Ammoniak) : "Der berühmte Entdecker des Acetals theilte mir damals gleichzeitig mit, dass sein Saüerstoffäther mit Ammoniakgas eine weisse krystallinische Verbingdung bilde; ... " (The famous discoverer of acetal [viz, Döbereiner] simultaneously communicated to me at that time that his ether oxide forms a white crystalline compound with ammonia gas; ... ) On p. 146, Liebig presented his empirical formula for 1-aminoethanol: C4H14N2O2. If the subscripts are divided by 2, the resulting formula is correct.
^Although it had long been assumed that the structure of 1-aminoethanol was CH3CH(OH)NH2, it had not been proven that 1-aminoethanol contained a hydroxyl (-OH) group until Schiff's investigation in 1877. See:
Schiff, Robert (1877) "Zur Constitution des Chloralammoniaks und des Aldehydammoniaks," Berichte der Deutschen Chemischen Gesellschaft, 10 : 165–171.
Aschan, Ossian (1915) "Neues über Aldehyd-ammoniak und Chloral-ammoniak." Berichte der Deutschen Chemischen Gesellschaft, 48 (1) : 874–891.
四月 01, 2023
氨基乙醇, 英語, aminoethanol, 是一种有机化合物, 化学式为ch3ch, 它被归类为烷醇胺, 具体来说, 它是2, 氨基乙醇的结构异构体, 这两种化合物的氨基位置不同, 由于的中心碳原子有四个不同的取代基, 因此该化合物有两种立体异构体, 与在商业中相当重要的2, 氨基乙醇不同, 不会作为纯物质出现, 主要具有理论意义, iupac名1, aminoethan, 氨基乙, 醇别名, 乙醛合氨识别cas号, pubchem, 522583chemspider, 455852smiles, oinchi. 1 氨基乙醇 英語 1 Aminoethanol 是一种有机化合物 化学式为CH3CH NH2 OH 它被归类为烷醇胺 具体来说 它是2 氨基乙醇的结构异构体 这两种化合物的氨基位置不同 由于1 氨基乙醇的中心碳原子有四个不同的取代基 因此该化合物有两种立体异构体 与在商业中相当重要的2 氨基乙醇不同 1 氨基乙醇不会作为纯物质出现 主要具有理论意义 1 氨基乙醇IUPAC名1 Aminoethan 1 ol1 氨基乙 1 醇别名 1 氨基乙醇乙醛合氨识别CAS号 75 39 8 PubChem 522583ChemSpider 455852SMILES CC N OInChI 1S C2H7NO c1 2 3 4 h2 4H 3H2 1H3InChIKey UJPKMTDFFUTLGM UHFFFAOYSA NEINECS 200 868 2性质化学式 C2H7NO摩尔质量 61 08 g mol 1若非注明 所有数据均出自标准状态 25 100 kPa 下 1 氨基乙醇存在于乙醛和氨水的溶液中 1 1 氨基乙醇被认为是丙氨酸合成的斯特雷克反应的中间体 2 历史 编辑1 氨基乙醇于1833年由德国化学家约翰 沃尔夫冈 德贝莱纳首先制备 其最简式最早由德国化学家尤斯图斯 冯 李比希于1835年确定 3 1 氨基乙醇的结构直到1877年仍未得到证实 当时德裔意大利化学家罗伯特 希夫证明其结构为 CH3CH OH NH2 4 参考资料 编辑 Smith Michael B March Jerry Advanced Organic Chemistry Reactions Mechanisms and Structure 6th New York Wiley Interscience 2007 ISBN 978 0 471 72091 1 Shinichi Yamabe Guixiang Zeng Wei Guan Shigeyoshi Sakaki Proton transfers in the Strecker reaction revealed by DFT calculations Beilstein Journal of Organic Chemistry 2014 10 1765 1774 PMC 4143099 PMID 25161735 doi 10 3762 bjoc 10 184 Liebig Justus 1835 Ueber die Producte der Oxydation des Alkohols On the products of oxidation of alcohol i e ethanol Annalen der Chemie 14 133 167 In 1821 Dobereiner had prepared what he called Sauerstoffather literally ether oxide which as Liebig later showed contained acetaldehyde On p 134 Liebig states that Dobereiner first produced 1 amino ethanol by perfusing acetaldehyde Sauerstoffather or Aldehyd as Liebig called it with ammonia gas Ammoniak Der beruhmte Entdecker des Acetals theilte mir damals gleichzeitig mit dass sein Sauerstoffather mit Ammoniakgas eine weisse krystallinische Verbingdung bilde The famous discoverer of acetal viz Dobereiner simultaneously communicated to me at that time that his ether oxide forms a white crystalline compound with ammonia gas On p 146 Liebig presented his empirical formula for 1 aminoethanol C4H14N2O2 If the subscripts are divided by 2 the resulting formula is correct Although it had long been assumed that the structure of 1 aminoethanol was CH3CH OH NH2 it had not been proven that 1 aminoethanol contained a hydroxyl OH group until Schiff s investigation in 1877 See Schiff Robert 1877 Zur Constitution des Chloralammoniaks und des Aldehydammoniaks Berichte der Deutschen Chemischen Gesellschaft 10 165 171 Aschan Ossian 1915 Neues uber Aldehyd ammoniak und Chloral ammoniak Berichte der Deutschen Chemischen Gesellschaft 48 1 874 891 取自 https zh wikipedia org w index php title 1 氨基乙醇 amp oldid 76583125, 维基百科，wiki，书籍，书籍，图书馆，
