^ 1.01.1Chao, G.; Sime, R. L.; Sime, R. J. Crystal and molecular structure of tris(acetylacetonato)ruthenium(III). Acta Crystallographica B. 1973, 29 (12): 2845. doi:10.1107/S0567740873007636.
^R.C. Mehrotra, R. Bohra, and D.P. Gaur "Metal β-Diketonates and Allied Derivatives", 1st ed.; Academic Press inc.: New York, 1978. ISBN0-12-488150-5.
^Barbieri, G. A. Systematic chemical investigations: ruthenium, rhodium, palladium. Atti Accad, Lincei. 1914, 23 (1): 334–40.
^Gupta, A. Improved synthesis and reactivity of tris(acetylacetonato)ruthenium(III). Indian Journal of Chemistry, Section A. 2000, 39A (4): 457. ISSN 0376-4710.
^Grobelny, R. The absorption spectra and magnetic properties of the chelated compounds of Ru(III) with β-diketones. Journal of Inorganic and Nuclear Chemistry. 1966, 28 (11): 2715–2718. doi:10.1016/0022-1902(66)80398-6.
^Paul Sharpe; N. George Alameddin; David E. Richardson. Alkyl Substituent Effects in the Redox Thermochemistry of Coordination Compounds: Oxidation and Reduction Energetics for Ruthenium Tris(β-diketonate) Complexes in Solution and the Gas Phase. Journal of the American Chemical Society. 1994, 116 (24): 11098–11108. doi:10.1021/ja00103a027.
^Richard D. Ernst, Enrique Melendez, Lothar Stahl, Manfred L. Ziegler. cis- and trans-Diene coordination in ruthenium(II) acetylacetonate compounds. Organometallics. 1991-10, 10 (10): 3635–3642 [2021-08-25]. ISSN 0276-7333. doi:10.1021/om00056a039（英语）.
^Bennett, M. A.; Byrnes, Matthew J.; Kováčik, Ivan. The fragment bis(acetylacetonato)ruthenium: a meeting-point of coordination and organometallic chemistry. Journal of Organometallic Chemistry. 2004, 689 (24): 4463. doi:10.1016/j.jorganchem.2004.07.027.
^Drake, A. F.; Gould, J. M.; Mason, S. F.; Rosini, C.; Woodley, F. J. The optical resolution of tris(pentane-2,4-dionato)metal(III) complexes. Polyhedron. 1983, 2 (6): 537–538. doi:10.1016/S0277-5387(00)87108-9.
二月 08, 2023
乙酰丙酮钌, 是一种乙酰丙酮配合物, 化学式ru, o2c5h7, 它是一种深紫色固体, 可溶于大多数有机溶剂, 它可用来制备其它钌化合物, iupac名tris, acetylacetonato, ruthenium, 别名, acac, 识别cas号, 14284, pubchem, 16057901smiles, inchi, 3c5h8o2, 性质化学式, c5h7o2, 3ru摩尔质量, 外观, 深紫色固体密度, 熔点, 溶解性, 不溶溶解性, 可溶于大部分有机溶剂危险性警示术语, r38安全术语, s3. 乙酰丙酮钌是一种乙酰丙酮配合物 化学式Ru O2C5H7 3 它是一种深紫色固体 可溶于大多数有机溶剂 2 它可用来制备其它钌化合物 乙酰丙酮钌IUPAC名Tris acetylacetonato Ruthenium III 别名 Ru acac 3乙酰丙酮钌 III 识别CAS号 14284 93 6 PubChem 16057901SMILES CC O CC O C CC O CC O C CC O CC O C Ru InChI 1S 3C5H8O2 Ru c3 1 4 6 3 5 2 7 h3 3H2 1 2H3 性质化学式 C5H7O2 3Ru摩尔质量 398 39 g mol 外观 深紫色固体密度 1 54 g cm3 1 熔点 260 C 533 K 溶解性 水 不溶溶解性 可溶于大部分有机溶剂危险性警示术语 R R36 R37 R38安全术语 S S26 S36若非注明 所有数据均出自标准状态 25 100 kPa 下 制备 编辑1914年 乙酰丙酮钌通过三氯化钌和乙酰丙酮在碳酸氢钾下的反应首次合成 3 从那时起 人们已经研究了替代合成路线 但原始的制备方法仍然有用 4 RuCl3 3H2O MeCOCH2COMe Ru acac 3 3 HCl 3 H2O结构和性质 编辑乙酰丙酮钌有 D3 对称性 六个氧原子以八面体构型围绕钌原子 乙酰丙酮钌中的Ru O 键长平均为 2 00 A 1 由于 Ru acac 3 是低自旋的 有一个d 电子 所以是顺磁性的 Ru acac 3 的磁化率 xM为 3 032 10 6 cm3 mol 有效磁矩 meff为 1 66 mB 5 在DMF溶液中 乙酰丙酮钌的氧化电位为 0 593 还原电位 1 223 V 相对于二茂铁 二茂铁阳离子对 6 Ru acac 3在烯烃存在下还原会形成二烯烃配合物 通常 此类反应是用锌在乙醇 1 3 二烯 7 中或锌汞齐在潮湿的四氢呋喃中进行的 8 2 Ru acac 3 4 alkene Zn 2 Ru acac 2 alkene 2 Zn acac 2产生的化合物是金属烯烃配合物的罕见例子 可以可逆地维持氧化 Ru acac 2 alkene 2 Ru acac 2 alkene 2 e 通过分离它和二苯甲酰基酒石酸的加合物 可拆分为单独的对映异构体 9 参考资料 编辑 1 0 1 1 Chao G Sime R L Sime R J Crystal and molecular structure of tris acetylacetonato ruthenium III Acta Crystallographica B 1973 29 12 2845 doi 10 1107 S0567740873007636 R C Mehrotra R Bohra and D P Gaur Metal b Diketonates and Allied Derivatives 1st ed Academic Press inc New York 1978 ISBN 0 12 488150 5 Barbieri G A Systematic chemical investigations ruthenium rhodium palladium Atti Accad Lincei 1914 23 1 334 40 Gupta A Improved synthesis and reactivity of tris acetylacetonato ruthenium III Indian Journal of Chemistry Section A 2000 39A 4 457 ISSN 0376 4710 Grobelny R The absorption spectra and magnetic properties of the chelated compounds of Ru III with b diketones Journal of Inorganic and Nuclear Chemistry 1966 28 11 2715 2718 doi 10 1016 0022 1902 66 80398 6 Paul Sharpe N George Alameddin David E Richardson Alkyl Substituent Effects in the Redox Thermochemistry of Coordination Compounds Oxidation and Reduction Energetics for Ruthenium Tris b diketonate Complexes in Solution and the Gas Phase Journal of the American Chemical Society 1994 116 24 11098 11108 doi 10 1021 ja00103a027 Richard D Ernst Enrique Melendez Lothar Stahl Manfred L Ziegler cis and trans Diene coordination in ruthenium II acetylacetonate compounds Organometallics 1991 10 10 10 3635 3642 2021 08 25 ISSN 0276 7333 doi 10 1021 om00056a039 英语 Bennett M A Byrnes Matthew J Kovacik Ivan The fragment bis acetylacetonato ruthenium a meeting point of coordination and organometallic chemistry Journal of Organometallic Chemistry 2004 689 24 4463 doi 10 1016 j jorganchem 2004 07 027 Drake A F Gould J M Mason S F Rosini C Woodley F J The optical resolution of tris pentane 2 4 dionato metal III complexes Polyhedron 1983 2 6 537 538 doi 10 1016 S0277 5387 00 87108 9 取自 https zh wikipedia org w index php title 乙酰丙酮钌 amp oldid 67640708, 维基百科，wiki，书籍，书籍，图书馆，
