^ 1.01.11.21.3Michael E. Jung, Michael J. Martinelli, George A. Olah, G. K. Surya Prakash, Jinbo Hu. Iodotrimethylsilane. October 15, 2005. ISBN 978-0471936237. doi:10.1002/047084289X.ri043.pub2.|journal=被忽略 (帮助)
^ 2.02.12.2Olah, G; Narang, S. C. Iodotrimethylsilane—a versatile synthetic reagent. Tetrahedron. 1982, 38 (15): 2225. doi:10.1016/0040-4020(82)87002-6.
^ (1988) "Cleavage of Methyl Ethers with Iodotrimethylsilane: Cyclohexanol from Cyclohexyl Methyl Ether". Org. Synth.; Coll. Vol.6: 353.
^GC/MS Analysis for Morphine and Other Opiates in Urine (PDF).[失效連結]
^Michael E. Jung; Mark A. Lyster. Quantitative dealkylation of alkyl ethers via treatment with trimethylsilyl iodide. A new method for ether hydrolysis. J. Org. Chem. 1977, 42 (23): 3761–3764. doi:10.1021/jo00443a033.
^Michael E. Jung; Mark A. Lyster. Conversion of alkyl carbamates into amines via treatment with trimethylsilyl iodide. J. Chem. Soc., Chem. Commun. 1978, (7): 315–316. doi:10.1039/C39780000315.
^Richard S. Lott; Virander S. Chauhan; Charles H. Stammer. Trimethylsilyl iodide as a peptide deblocking agent. J. Chem. Soc., Chem. Commun. 1979, (11): 495–496. doi:10.1039/C39790000495.
^Zhijian Liu; Nobuyoshi Yasuda; Michael Simeone; Robert A. Reamer. N-Boc Deprotection and Isolation Method for Water-Soluble Zwitterionic Compounds. J. Org. Chem. 2014, 79 (23): 11792–11796. PMID 25376704. doi:10.1021/jo502319z.
一月 29, 2023
三甲基碘硅烷, 又称三甲基碘化硅或, tmsi, 是一种有机硅化合物, 化学式为, 3sii, 它在室温下是一种无色挥发性液体, iupac名iodo, trimethyl, silane别名, 碘三甲基硅烷, tmsi, jung, 试剂识别cas号, 16029, pubchem, 85247chemspider, 76879smiles, cinchi, c3h9isi, 3h3inchikey, csrzqmiraztjoy, uhfffaoyab性质化学式, c3h9isi摩尔质量, 1外观, 清澈无色液. 三甲基碘硅烷 又称三甲基碘化硅或 TMSI 是一种有机硅化合物 化学式为 CH3 3SiI 它在室温下是一种无色挥发性液体 三甲基碘硅烷IUPAC名Iodo trimethyl silane别名 碘三甲基硅烷 TMSI TMS I Jung 试剂识别CAS号 16029 98 4 PubChem 85247ChemSpider 76879SMILES I Si C C CInChI 1 C3H9ISi c1 5 2 3 4 h1 3H3InChIKey CSRZQMIRAZTJOY UHFFFAOYAB性质化学式 C3H9ISi摩尔质量 200 09 g mol 1外观 清澈无色液体 1 密度 1 406 g mL 1 沸点 106 C 109 C 1 危险性闪点 31 C 242 K 1 若非注明 所有数据均出自一般条件 25 100 kPa 下 制备 编辑三甲基碘硅烷可以由六甲基乙硅烷和碘单质反应而成 2 它也可以由六甲基二硅氧烷和三碘化铝的反应生成 2 3 TMS TMS I2 2 TMSI TMS CH3 3Si 3 TMS O TMS 2 AlI3 6 TMSI Al2O3应用 编辑三甲基碘硅烷可以给醇类 ROH 引入三甲基硅基 R OH TMSI R OTMS HI由于所得的硅醚比原料 醇 的挥发性更大 因此这种类型的反应对于气相色谱分析可能有用 4 但是 对于制备本体三甲基硅烷基卤的材料 由于三甲基氯硅烷的成本较低 因此是优选的 TMSI会和醚 ROR 反应 形成碘代烃和三甲基硅基醚 ROSiMe3 其水解可以生成醇 5 三甲基碘硅烷可以用来移除叔丁氧羰基 2 6 7 并适用于其他脱保护方法不可行的情况下 8 参考资料 编辑 1 0 1 1 1 2 1 3 Michael E Jung Michael J Martinelli George A Olah G K Surya Prakash Jinbo Hu Iodotrimethylsilane October 15 2005 ISBN 978 0471936237 doi 10 1002 047084289X ri043 pub2 journal 被忽略 帮助 2 0 2 1 2 2 Olah G Narang S C Iodotrimethylsilane a versatile synthetic reagent Tetrahedron 1982 38 15 2225 doi 10 1016 0040 4020 82 87002 6 1988 Cleavage of Methyl Ethers with Iodotrimethylsilane Cyclohexanol from Cyclohexyl Methyl Ether Org Synth Coll Vol 6 353 GC MS Analysis for Morphine and Other Opiates in Urine PDF 失效連結 Michael E Jung Mark A Lyster Quantitative dealkylation of alkyl ethers via treatment with trimethylsilyl iodide A new method for ether hydrolysis J Org Chem 1977 42 23 3761 3764 doi 10 1021 jo00443a033 Michael E Jung Mark A Lyster Conversion of alkyl carbamates into amines via treatment with trimethylsilyl iodide J Chem Soc Chem Commun 1978 7 315 316 doi 10 1039 C39780000315 Richard S Lott Virander S Chauhan Charles H Stammer Trimethylsilyl iodide as a peptide deblocking agent J Chem Soc Chem Commun 1979 11 495 496 doi 10 1039 C39790000495 Zhijian Liu Nobuyoshi Yasuda Michael Simeone Robert A Reamer N Boc Deprotection and Isolation Method for Water Soluble Zwitterionic Compounds J Org Chem 2014 79 23 11792 11796 PMID 25376704 doi 10 1021 jo502319z 取自 https zh wikipedia org w index php title 三甲基碘硅烷 amp oldid 74083126, 维基百科，wiki，书籍，书籍，图书馆，
