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^R. J. Rahaim & J. T. Shaw. Zinc-Catalyzed Silylation of Terminal Alkynes. J. Org. Chem. 2008, 73 (7): 2912–2915. PMID 18331056. doi:10.1021/jo702557d.
^J. E. D. Kirkham, T. D. L. Courtney, V. Lee and J. E. Baldwin. Asymmetric synthesis of cytotoxic sponge metabolites R-strongylodiols A and B and an analogue. Tetrahedron. 2005, 61 (30): 7219–7232. doi:10.1016/j.tet.2005.05.034.
^J. Lombard, S. Romain, S. Dumas, J. Chauvin, M.-N. Collomb, D. Daveloose, A. Deronzier and J.-C. Leprêtre. Tetranuclear Polypyridyl Complexes of RuII and FeII: Synthesis, Electrochemical, Photophysical and Photochemical Behaviour. European Journal of Inorganic Chemistry. 2005, 2005 (16): 3320–3330. doi:10.1002/ejic.200500106.
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一月 30, 2023
三氟甲磺酸锌, 是锌的三氟甲磺酸盐, 它通常用作路易斯酸催化剂, 例如用于硅烷化反应, 英语, silylation, iupac名zinc, trifluoromethanesulfonate识别cas号, 54010, npubchem, 104671chemspider, 94493smiles, oinchi, 2chf3o3s, 2inchikey, citilbvtayewkr, nuqvwonbaz性质化学式, c2f6o6s2zn摩尔质量, 1外观, white, powder若非注明, 所有数据均. 三氟甲磺酸锌是锌的三氟甲磺酸盐 它通常用作路易斯酸催化剂 例如用于硅烷化反应 英语 silylation 1 三氟甲磺酸锌IUPAC名zinc trifluoromethanesulfonate识别CAS号 54010 75 2 NPubChem 104671ChemSpider 94493SMILES Zn 2 FC F F S O O O FC F F S O O OInChI 1 2CHF3O3S Zn c2 2 1 3 4 8 5 6 7 h2 H 5 6 7 q 2 p 2InChIKey CITILBVTAYEWKR NUQVWONBAZ性质化学式 C2F6O6S2Zn摩尔质量 363 55 g mol 1外观 White powder若非注明 所有数据均出自一般条件 25 100 kPa 下 三氟甲磺酸锌是白色粉末 尽管它存在市售品 但是一些科研人员会通过不同的方法制备它 2 3 例如 它可以由三氟甲磺酸和金属锌在丙酮中反应得到 4 或者在甲醇中和碳酸锌反应来制备 5 Zn 2 HOTf Zn OTf 2 H2 ZnCO3 2 HOTf Zn OTf 2 H2O CO2 OTf CF3SO2 参考文献 编辑 H Jiang amp S Zhu Silylation of 1 alkynes with chlorosilanes promoted by Zn OTf 2 an efficient way to the preparation of alkynylsilanes Tetrahedron Letters 2005 46 3 517 519 doi 10 1016 j tetlet 2004 10 175 R J Rahaim amp J T Shaw Zinc Catalyzed Silylation of Terminal Alkynes J Org Chem 2008 73 7 2912 2915 PMID 18331056 doi 10 1021 jo702557d J E D Kirkham T D L Courtney V Lee and J E Baldwin Asymmetric synthesis of cytotoxic sponge metabolites R strongylodiols A and B and an analogue Tetrahedron 2005 61 30 7219 7232 doi 10 1016 j tet 2005 05 034 J Lombard S Romain S Dumas J Chauvin M N Collomb D Daveloose A Deronzier and J C Lepretre Tetranuclear Polypyridyl Complexes of RuII and FeII Synthesis Electrochemical Photophysical and Photochemical Behaviour European Journal of Inorganic Chemistry 2005 2005 16 3320 3330 doi 10 1002 ejic 200500106 E J Corey amp K Shimoji Magnesium and zinc catalyzed thioketalization Tetrahedron Letters 1983 24 2 169 172 doi 10 1016 S0040 4039 00 81357 X 取自 https zh wikipedia org w index php title 三氟甲磺酸锌 amp oldid 49480272, 维基百科，wiki，书籍，书籍，图书馆，
