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维基百科

2,4-二羟基-6-甲基苯甲醛

行進 31, 2023

2,4-二羟基-6-甲基苯甲醛是一种有机化合物，化学式为C8H8O3，它是一些真菌的天然产物，如灰樹花[2]、Aspergillus cleistominutus（英语：Aspergillus cleistominutus）[3]、小巢狀麴菌[4]和Agrocybe praecox（英语：Agrocybe praecox）[5]等。

2,4-二羟基-6-甲基苯甲醛
IUPAC名
2,4-Dihydroxy-6-methylbenzaldehyde
别名
  • * Orcylaldehyde
    • Orcinaldehyde
    • Orcylic aldehyde
    • 6-Methyl-β-resorcyladehyde
识别
CAS号 487-69-4
PubChem 251690
ChemSpider 220511
SMILES
InChI
InChIKey LJFQTUKKYWDRAT-UHFFFAOYSA-N
ChEBI 155863
性质
化学式 C8H8O3
摩尔质量 152.15 g·mol−1
外观 无色
熔点 181－183 °C（454－456 K）[1]
沸点 321.9 °C（595 K）
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

它可由苔黑酚和氰化锌在氯化氢下进行加特曼反应[1]，再经水解得到。[1][6]

参考文献

  1. ^ 1.0 1.1 1.2 Rao, K Ranganatha; Seshadri, T. R. Synthesis of 7-hydroxy-5-methylcoumarin. Proceeding of the Indian Academy of Sciences. April 1941, 13 (4): 255 [2022-12-25]. S2CID 81699243. doi:10.1007/BF03048997. （原始内容于2022-05-16）. 
  2. ^ Lin, Jiun-Tsai; Liu, Wen-Hsiung. ο-Orsellinaldehyde from the Submerged Culture of the Edible Mushroom Grifola frondosa Exhibits Selective Cytotoxic Effect Against Hep 3B Cells Through Apoptosis (PDF). Journal of Agricultural and Food Chemistry. 1 October 2006, 54 (20): 7564–7569 [2022-12-25]. PMID 17002422. doi:10.1021/jf0616762. （原始内容 (PDF)于2022-12-25）. 
  3. ^ Chen, A.J.; Frisvad, J.C.; Sun, B.D.; Varga, J.; Kocsubé, S.; Dijksterhuis, J.; Kim, D.H.; Hong, S.-B.; Houbraken, J.; Samson, R.A. Aspergillus section Nidulantes (formerly Emericella ): Polyphasic taxonomy, chemistry and biology. Studies in Mycology. 1 June 2016, 84 (1): 1–118. PMC 5198626  . PMID 28050053. doi:10.1016/j.simyco.2016.10.001. 
  4. ^ Ahuja, Manmeet; Chiang, Yi-Ming; Chang, Shu-Lin; Praseuth, Mike B.; Entwistle, Ruth; Sanchez, James F.; Lo, Hsien-Chun; Yeh, Hsu-Hua; Oakley, Berl R.; Wang, Clay C. C. Illuminating the Diversity of Aromatic Polyketide Synthases in Aspergillus nidulans. Journal of the American Chemical Society. 16 May 2012, 134 (19): 8212–8221. PMC 3357392  . PMID 22510154. doi:10.1021/ja3016395 （英语）. 
  5. ^ Fushimi, Keiji; Anzai, Kota; Tokuyama, Shinji; Kiriiwa, Yoshikazu; Matsumoto, Noriyuki; Sekiya, Atsushi; Hashizume, Daisuke; Nagasawa, Kazuo; Hirai, Hirofumi; Kawagishi, Hirokazu. Agrocybynes A–E from the culture broth of Agrocybe praecox. Tetrahedron. January 2012, 68 (4): 1262–1265. S2CID 51767920. doi:10.1016/J.TET.2011.11.049. hdl:10297/6698. 
  6. ^ Gattermann, L.; Köbner, M. Synthese von Oxyaldehyden der Benzolreihe. Berichte der Deutschen Chemischen Gesellschaft. January 1899, 32 (1): 278–283. doi:10.1002/cber.18990320144 （德语）. 

行進 31, 2023
二羟基, 甲基苯甲醛, 是一种有机化合物, 化学式为c8h8o3, 它是一些真菌的天然产物, 如灰樹花, aspergillus, cleistominutus, 英语, aspergillus, cleistominutus, 小巢狀麴菌, 和agrocybe, praecox, 英语, agrocybe, praecox, iupac名2, dihydroxy, methylbenzaldehyde别名, orcylaldehyde, orcinaldehyde, orcylic, aldehyde, meth. 2 4 二羟基 6 甲基苯甲醛是一种有机化合物 化学式为C8H8O3 它是一些真菌的天然产物 如灰樹花 2 Aspergillus cleistominutus 英语 Aspergillus cleistominutus 3 小巢狀麴菌 4 和Agrocybe praecox 英语 Agrocybe praecox 5 等 2 4 二羟基 6 甲基苯甲醛IUPAC名2 4 Dihydroxy 6 methylbenzaldehyde别名 Orcylaldehyde Orcinaldehyde Orcylic aldehyde 6 Methyl b resorcyladehyde识别CAS号 487 69 4PubChem 251690ChemSpider 220511SMILES CC1 CC CC C1C O O OInChI 1S C8H8O3 c1 5 2 6 10 3 8 11 7 5 4 9 h2 4 10 11H 1H3InChIKey LJFQTUKKYWDRAT UHFFFAOYSA NChEBI 155863性质化学式 C8H8O3摩尔质量 152 15 g mol 1外观 无色熔点 181 183 C 454 456 K 1 沸点 321 9 C 595 K 若非注明 所有数据均出自标准状态 25 100 kPa 下 它可由苔黑酚和氰化锌在氯化氢下进行加特曼反应 1 再经水解得到 1 6 参考文献 编辑 1 0 1 1 1 2 Rao K Ranganatha Seshadri T R Synthesis of 7 hydroxy 5 methylcoumarin Proceeding of the Indian Academy of Sciences April 1941 13 4 255 2022 12 25 S2CID 81699243 doi 10 1007 BF03048997 原始内容存档于2022 05 16 Lin Jiun Tsai Liu Wen Hsiung o Orsellinaldehyde from the Submerged Culture of the Edible Mushroom Grifola frondosa Exhibits Selective Cytotoxic Effect Against Hep 3B Cells Through Apoptosis PDF Journal of Agricultural and Food Chemistry 1 October 2006 54 20 7564 7569 2022 12 25 PMID 17002422 doi 10 1021 jf0616762 原始内容存档 PDF 于2022 12 25 Chen A J Frisvad J C Sun B D Varga J Kocsube S Dijksterhuis J Kim D H Hong S B Houbraken J Samson R A Aspergillus section Nidulantes formerly Emericella Polyphasic taxonomy chemistry and biology Studies in Mycology 1 June 2016 84 1 1 118 PMC 5198626 PMID 28050053 doi 10 1016 j simyco 2016 10 001 Ahuja Manmeet Chiang Yi Ming Chang Shu Lin Praseuth Mike B Entwistle Ruth Sanchez James F Lo Hsien Chun Yeh Hsu Hua Oakley Berl R Wang Clay C C Illuminating the Diversity of Aromatic Polyketide Synthases in Aspergillus nidulans Journal of the American Chemical Society 16 May 2012 134 19 8212 8221 PMC 3357392 PMID 22510154 doi 10 1021 ja3016395 英语 Fushimi Keiji Anzai Kota Tokuyama Shinji Kiriiwa Yoshikazu Matsumoto Noriyuki Sekiya Atsushi Hashizume Daisuke Nagasawa Kazuo Hirai Hirofumi Kawagishi Hirokazu Agrocybynes A E from the culture broth of Agrocybe praecox Tetrahedron January 2012 68 4 1262 1265 S2CID 51767920 doi 10 1016 J TET 2011 11 049 hdl 10297 6698 Gattermann L Kobner M Synthese von Oxyaldehyden der Benzolreihe Berichte der Deutschen Chemischen Gesellschaft January 1899 32 1 278 283 doi 10 1002 cber 18990320144 德语 取自 https zh wikipedia org w index php title 2 4 二羟基 6 甲基苯甲醛 amp oldid 75461844, 维基百科，wiki，书籍，书籍，图书馆，

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