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维基百科

1-硝基萘

十月 05, 2023

1-硝基萘是一种有机化合物，化学式为C10H7NO2。它可由萘的硝化反应制备，硝硫混酸是最常见的硝化试剂，[4][5]也有文献报道使用硝酸铋[6]、二氧化氮[7]、N-硝基糖精[8]等进行硝化反应。它可以被还原剂（如氢气[9]、硼氢化钠[10]、水合肼[11]等）还原为1-萘胺。

1-硝基萘
别名 α-硝基萘
识别
CAS号 86-57-7  
PubChem 6849
ChemSpider 6588
SMILES
 
  • C1=CC=C2C(=C1)C=CC=C2[N+](=O)[O-]
Beilstein 1867714
UN编号 2538
EINECS 201-684-5
ChEBI 34104
KEGG C14040
性质
化学式 C10H7NO2
摩尔质量 173.17 g·mol−1
外观 浅黄色固体
密度 1.332 g·cm−3[1]
熔点 59 °C（332 K）[2]
溶解性（水） 0.0035 g（25 °C）[3]
危险性
GHS危险性符号
GHS提示词 危险
H-术语 H228, H301, H315, H319, H335, H351, H411
P-术语 P201, P202, P210, P240, P241, P261, P264, P270, P271, P273, P280, P281, P301+310, P302+352
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

参考文献 编辑

  1. ^ "Hazardous Substances Data Bank" data were obtained from the National Library of Medicine (US). Retrieved from SciFinder. [2020-12-28].
  2. ^ Badgujar, D. M.; Talwar, M. B.; Asthana, S. N.; Mahulikar, P. P. Environmentally benign synthesis of aromatic nitro compounds using silica supported inorganic nitrates. Journal of Scientific & Industrial Research, 2007. 66 (3): 250-251. ISSN: 0022-4456.
  3. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2020 ACD/Labs). Retrieved from SciFinder. [2020-12-28].
  4. ^ Khabarov, Yu. G.; Veshnyakov, V. A.; Snigirev, I. A. Method for producing 1-nitronaphthalene. 2018. RU 2669774 C1.
  5. ^ Gerald Booth. Wiley-VCH Verlag GmbH & Co. KGaA , 编. Naphthalene Derivatives. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA. 2000-06-15 [2020-12-28]. ISBN 9783527306732. doi:10.1002/14356007.a17_009 （英语）. 
  6. ^ Susanta Samajdar, Frederick F Becker, Bimal K Banik. Surface-mediated highly efficient regioselective nitration of aromatic compounds by bismuth nitrate. Tetrahedron Letters. 2000-10, 41 (42): 8017–8020 [2020-12-28]. doi:10.1016/S0040-4039(00)01397-6. （原始内容于2018-06-27） （英语）. 
  7. ^ Kuiyi You, Zhongcang Zhou, Jian Jian, Renjie Deng, Pingle Liu, Qiuhong Ai, He’an Luo. A simple approach for preparation of dinitronaphthalene compounds from the nitration reaction of 1-nitronaphthalene with NO2 as nitration reagent. Research on Chemical Intermediates. 2015-11, 41 (11): 8307–8315 [2020-12-28]. ISSN 0922-6168. doi:10.1007/s11164-014-1893-1 （英语）. 
  8. ^ Roxan Calvo, Kun Zhang, Alessandro Passera, Dmitry Katayev. Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin. Nature Communications. 2019-12, 10 (1) [2020-12-28]. ISSN 2041-1723. PMC 6667458  . PMID 31363083. doi:10.1038/s41467-019-11419-y. （原始内容于2019-11-15） （英语）. 
  9. ^ Huan Fu, Luna Ruan, Jianhua Liao, An Pei, Jun Liu, Li Zeng, Kai Yang, Lihua Zhu, Bing Hui Chen. PtNi/C bimetallic nanocatalyst with high catalytic performance and stability for 1-nitronaphthalene hydorgenation to 1-naphthylamine. Molecular Catalysis. 2020-10, 494: 111151 [2020-12-28]. doi:10.1016/j.mcat.2020.111151 （英语）. 
  10. ^ Haydar Göksu, Nursefa Zengin, Hakan Burhan, Kemal Cellat, Fatih Şen. . Scientific Reports. 2020-12, 10 (1) [2020-12-28]. ISSN 2045-2322. PMC 7229225  . PMID 32415148. doi:10.1038/s41598-020-64988-0. （原始内容存档于2021-10-02） （英语）. 
  11. ^ Upendra Sharma, Praveen Kumar Verma, Neeraj Kumar, Vishal Kumar, Manju Bala, Bikram Singh. Phosphane-Free Green Protocol for Selective Nitro Reduction with an Iron-Based Catalyst. Chemistry - A European Journal. 2011-05-16, 17 (21): 5903–5907 [2020-12-28]. doi:10.1002/chem.201003621 （英语）. 

十月 05, 2023
硝基萘, 是一种有机化合物, 化学式为c10h7no2, 它可由萘的硝化反应制备, 硝硫混酸是最常见的硝化试剂, 也有文献报道使用硝酸铋, 二氧化氮, 硝基糖精, 等进行硝化反应, 它可以被还原剂, 如氢气, 硼氢化钠, 水合肼, 还原为1, 萘胺, 别名, 硝基萘识别cas号, pubchem, 6849chemspider, 6588smiles, beilstein, 1867714un编号, 2538einecs, 5chebi, 34104kegg, c14040性质化学式, c10h7no2摩尔质量, . 1 硝基萘是一种有机化合物 化学式为C10H7NO2 它可由萘的硝化反应制备 硝硫混酸是最常见的硝化试剂 4 5 也有文献报道使用硝酸铋 6 二氧化氮 7 N 硝基糖精 8 等进行硝化反应 它可以被还原剂 如氢气 9 硼氢化钠 10 水合肼 11 等 还原为1 萘胺 1 硝基萘别名 a 硝基萘识别CAS号 86 57 7 PubChem 6849ChemSpider 6588SMILES C1 CC C2C C1 C CC C2 N O O Beilstein 1867714UN编号 2538EINECS 201 684 5ChEBI 34104KEGG C14040性质化学式 C10H7NO2摩尔质量 173 17 g mol 1外观 浅黄色固体密度 1 332 g cm 3 1 熔点 59 C 332 K 2 溶解性 水 0 0035 g 25 C 3 危险性GHS危险性符号GHS提示词 危险H 术语 H228 H301 H315 H319 H335 H351 H411P 术语 P201 P202 P210 P240 P241 P261 P264 P270 P271 P273 P280 P281 P301 310 P302 352若非注明 所有数据均出自标准状态 25 100 kPa 下 参考文献 编辑 Hazardous Substances Data Bank data were obtained from the National Library of Medicine US Retrieved from SciFinder 2020 12 28 Badgujar D M Talwar M B Asthana S N Mahulikar P P Environmentally benign synthesis of aromatic nitro compounds using silica supported inorganic nitrates Journal of Scientific amp Industrial Research 2007 66 3 250 251 ISSN 0022 4456 Calculated using Advanced Chemistry Development ACD Labs Software V11 02 c 1994 2020 ACD Labs Retrieved from SciFinder 2020 12 28 Khabarov Yu G Veshnyakov V A Snigirev I A Method for producing 1 nitronaphthalene 2018 RU 2669774 C1 Gerald Booth Wiley VCH Verlag GmbH amp Co KGaA 编 Naphthalene Derivatives Weinheim Germany Wiley VCH Verlag GmbH amp Co KGaA 2000 06 15 2020 12 28 ISBN 9783527306732 doi 10 1002 14356007 a17 009 英语 Susanta Samajdar Frederick F Becker Bimal K Banik Surface mediated highly efficient regioselective nitration of aromatic compounds by bismuth nitrate Tetrahedron Letters 2000 10 41 42 8017 8020 2020 12 28 doi 10 1016 S0040 4039 00 01397 6 原始内容存档于2018 06 27 英语 Kuiyi You Zhongcang Zhou Jian Jian Renjie Deng Pingle Liu Qiuhong Ai He an Luo A simple approach for preparation of dinitronaphthalene compounds from the nitration reaction of 1 nitronaphthalene with NO2 as nitration reagent Research on Chemical Intermediates 2015 11 41 11 8307 8315 2020 12 28 ISSN 0922 6168 doi 10 1007 s11164 014 1893 1 英语 Roxan Calvo Kun Zhang Alessandro Passera Dmitry Katayev Facile access to nitroarenes and nitroheteroarenes using N nitrosaccharin Nature Communications 2019 12 10 1 2020 12 28 ISSN 2041 1723 PMC 6667458 nbsp PMID 31363083 doi 10 1038 s41467 019 11419 y 原始内容存档于2019 11 15 英语 引文格式1维护 PMC格式 link Huan Fu Luna Ruan Jianhua Liao An Pei Jun Liu Li Zeng Kai Yang Lihua Zhu Bing Hui Chen PtNi C bimetallic nanocatalyst with high catalytic performance and stability for 1 nitronaphthalene hydorgenation to 1 naphthylamine Molecular Catalysis 2020 10 494 111151 2020 12 28 doi 10 1016 j mcat 2020 111151 英语 Haydar Goksu Nursefa Zengin Hakan Burhan Kemal Cellat Fatih Sen A Novel Hydrogenation of Nitroarene Compounds with Multi Wall Carbon Nanotube Supported Palladium Copper Nanoparticles PdCu MWCNT NPs in Aqueous Medium Scientific Reports 2020 12 10 1 2020 12 28 ISSN 2045 2322 PMC 7229225 nbsp PMID 32415148 doi 10 1038 s41598 020 64988 0 原始内容存档于2021 10 02 英语 引文格式1维护 PMC格式 link Upendra Sharma Praveen Kumar Verma Neeraj Kumar Vishal Kumar Manju Bala Bikram Singh Phosphane Free Green Protocol for Selective Nitro Reduction with an Iron Based Catalyst Chemistry A European Journal 2011 05 16 17 21 5903 5907 2020 12 28 doi 10 1002 chem 201003621 英语 取自 https zh wikipedia org w index php title 1 硝基萘 amp oldid 76275737, 维基百科，wiki，书籍，书籍，图书馆，

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