^ 1.01.1Georg Brauer (Hrsg.): Handbuch der Präparativen Anorganischen Chemie. 3., umgearb. Auflage. Band II. Enke, Stuttgart 1978, ISBN 3-432-87813-3, S. 1245.
^Day Jr R A, Wilhite R N, Hamilton F D. Stability of complexes of uranium (IV) with chloride, sulfate and thiocyanate[J]. Journal of the American Chemical Society, 1955, 77(12): 3180-3182. DOI: 10.1021/ja01617a004
^Hennig C, Kraus W, Emmerling F, et al. Coordination of a uranium (IV) sulfate monomer in an aqueous solution and in the solid state[J]. Inorganic chemistry, 2008, 47(5): 1634-1638. DOI: 10.1021/ic701880h
拓展阅读编辑
Perez, F. M.; Gil, J. M.; Gil, F. J. M. Preparation, infrared and visible spectra of Sulfate Complexes of Uranium(IV). Zeitschrift für anorganische und allgemeine Chemie. 1980, 462: 231. doi:10.1002/zaac.19804620127.
Merkel, B.; Hasche-Berger, A. (2008). Uranium, Mining and Hydrogeology. Springer. ISBN978-3-540-87745-5
Hennig, C.; Schmeide, K.; Brendler, V.; Moll, H.; Tsushima, S.; Scheinost, A.C. (2007). “EXAFS Investigation of U(VI), U(IV), and Th(IV) Sulfato Complexes in Aqueous Solution”. Inorganic Chemistry 46 (15): 5882–5892.
Cardenas, E.; Watson, D.; Gu, B.; Ginder-Vogel, M.; Kitanidis, P.K.; Jardin, P.M.; Wu, W.; Leigh, M.B.; Carley, J.; Carroll, S.; Gentry, T.; Luoe, J.; Zhou, J.; Criddle, C.S.; Marsh, T.L.; Tiedje, J.M. (2010). “Significant Association between Sulfate-Reducing Bacteria and Uranium-Reducing Microbial Communities as Revealed by a Combined Massively Parallel Sequencing-Indicator Species Approach”. Applied and Environmental Microbiology 76 (20): 6778-6786.
Converse, B.J.; Wua, T.; Findlay, R.H.; Roden, E.E. (2013). “U(VI) Reduction in Sulfate-Reducing Subsurface Sediments Amended with Ethanol or Acetate”. Applied and Environmental Microbiology 79 (13): 4173-4177.
Day, R. A.; Wilhite, R. N.; Hamilton, F.R. (1955). “Stability of Complexes of Uranium(IV) with Chloride, Sulfate and Thiocyanate”. Journal of the American Chemical Society 77 (12):3180-3182.
Hennig, C.; Kraus, W.; Emmerling, F.; Ikeda, A.;. Scheinost, A.C. (2008). “Coordination of a Uranium(IV) Sulfate Monomer in an Aqueous Solution and in the Solid State”. Inorganic Chemistry 47 (5): 1634-1638.
Plášil, J.; Fejfarová, K.; Novák, M.; Dušek, M.; Škoda, R.; Hloušek, J.; Čejka, J.; Majzlan, J.; Sejkora, J.; Machovič, V.; Talla, D. (2011). “Běhounekite, U(SO4)2(H2O)4, from Jáchymov (St Joachimsthal), Czech Republic: the first natural U4+ sulphate”. Mineralogical Magazine 75 (6): 2739-2753.
Mudd, G.M. (2001). “Critical Review of Acid in situ leach uranium mining: 1. USA and Australia”. Environmental Geology 41 (3-4): 390-403.
Závodská, L.; Kosorínová, E.; Scerbáková, L.; Lesny, J. (2008). “Environmental Chemistry of Uranium”. HV ISSN 1418-7108.
十二月 06, 2023
硫酸铀, 是一种水溶性铀化合物, 化学式为u, 高毒, displaystyle, mathrm, biggl, displaystyle, mathrm, biggr, 英文名, uranium, sulfate别名, 硫酸铀, 二硫酸铀识别cas号, 14355, 无水, y13470, 四水, y19086, 八水, ychemspider, 11383849smiles, oinchi, h2o4s, 2inchikey, smwcbvijchhbau, nuqvwonbad性质化学式, 2摩尔质量, 无水. 硫酸铀 IV 是一种水溶性铀化合物 化学式为U SO4 2 高毒 硫酸铀 IV displaystyle mathrm Biggl 2 displaystyle mathrm Biggr 2 英文名 Uranium IV sulfate别名 硫酸铀 二硫酸铀识别CAS号 14355 39 6 无水 Y13470 23 0 四水 Y19086 22 7 八水 YChemSpider 11383849SMILES U 4 O S O O O O S O O OInChI 1 H2O4S U c1 5 2 3 4 h H2 1 2 3 4 q 2 p 2InChIKey SMWCBVIJCHHBAU NUQVWONBAD性质化学式 U SO4 2摩尔质量 430 15 无水 502 22 四水 g mol 密度 3 6 g cm 3 四水 1 相关物质其他阴离子 四氯化铀其他阳离子 硫酸钕硫酸钍相关化学品 二氧化铀硫酸铀酰若非注明 所有数据均出自标准状态 25 100 kPa 下 目录 1 制备 2 相关物种 3 参考文献 4 拓展阅读制备 编辑硫酸铀酰溶液经过光化学还原可以得到硫酸铀 IV 以乙醇为还原剂 光化学还原可以在日光下进行 硫酸铀 IV 在溶液中结晶 或者加入过量的乙醇使之沉淀 硫酸铀有多种水合物 这种光化学反应在热力学和动力学上都是有利的 硫酸铀酰阴极还原也能得到硫酸铀 IV 1 UO2SO4 2H2SO4 U SO4 2 4H2O相关物种 编辑UIV SO4可以形成离子及配合物 如USO42 2 U SO4 5 H2O 6 3 等 参考文献 编辑 1 0 1 1 Georg Brauer Hrsg Handbuch der Praparativen Anorganischen Chemie 3 umgearb Auflage Band II Enke Stuttgart 1978 ISBN 3 432 87813 3 S 1245 Day Jr R A Wilhite R N Hamilton F D Stability of complexes of uranium IV with chloride sulfate and thiocyanate J Journal of the American Chemical Society 1955 77 12 3180 3182 DOI 10 1021 ja01617a004 Hennig C Kraus W Emmerling F et al Coordination of a uranium IV sulfate monomer in an aqueous solution and in the solid state J Inorganic chemistry 2008 47 5 1634 1638 DOI 10 1021 ic701880h拓展阅读 编辑Perez F M Gil J M Gil F J M Preparation infrared and visible spectra of Sulfate Complexes of Uranium IV Zeitschrift fur anorganische und allgemeine Chemie 1980 462 231 doi 10 1002 zaac 19804620127 Merkel B Hasche Berger A 2008 Uranium Mining and Hydrogeology Springer ISBN 978 3 540 87745 5 Hennig C Schmeide K Brendler V Moll H Tsushima S Scheinost A C 2007 EXAFS Investigation of U VI U IV and Th IV Sulfato Complexes in Aqueous Solution Inorganic Chemistry 46 15 5882 5892 Cardenas E Watson D Gu B Ginder Vogel M Kitanidis P K Jardin P M Wu W Leigh M B Carley J Carroll S Gentry T Luoe J Zhou J Criddle C S Marsh T L Tiedje J M 2010 Significant Association between Sulfate Reducing Bacteria and Uranium Reducing Microbial Communities as Revealed by a Combined Massively Parallel Sequencing Indicator Species Approach Applied and Environmental Microbiology 76 20 6778 6786 Converse B J Wua T Findlay R H Roden E E 2013 U VI Reduction in Sulfate Reducing Subsurface Sediments Amended with Ethanol or Acetate Applied and Environmental Microbiology 79 13 4173 4177 Day R A Wilhite R N Hamilton F R 1955 Stability of Complexes of Uranium IV with Chloride Sulfate and Thiocyanate Journal of the American Chemical Society 77 12 3180 3182 Hennig C Kraus W Emmerling F Ikeda A Scheinost A C 2008 Coordination of a Uranium IV Sulfate Monomer in an Aqueous Solution and in the Solid State Inorganic Chemistry 47 5 1634 1638 Plasil J Fejfarova K Novak M Dusek M Skoda R Hlousek J Cejka J Majzlan J Sejkora J Machovic V Talla D 2011 Behounekite U SO4 2 H2O 4 from Jachymov St Joachimsthal Czech Republic the first natural U4 sulphate Mineralogical Magazine 75 6 2739 2753 Mudd G M 2001 Critical Review of Acid in situ leach uranium mining 1 USA and Australia Environmental Geology 41 3 4 390 403 Zavodska L Kosorinova E Scerbakova L Lesny J 2008 Environmental Chemistry of Uranium HV ISSN 1418 7108 取自 https zh wikipedia org w index php title 硫酸铀 IV amp oldid 68898175, 维基百科,wiki,书籍,书籍,图书馆,