奥林匹克烷

奥林匹克烷（Olympiadane）是一种機械互鎖結構分子，由五个类似奥运五环的互锁大环组成。分子是线性五联环烃或[5]索烃。它由Fraser Stoddart（英语：Fraser Stoddart）及其同事于1994年合成并命名^[1]。该分子出于对有机合成的可能性探索^[2]，并未考虑任何实际用途。类似的链环烃可能会用于分子计算机的构建。

奥林匹克烷
IUPAC名 6,9,12,15,18,29,32,35,38,41,52,55,58,61,64-pentadecaoxaheptacyclo[63.4.0.0^5,69.0^19,24.0^23,28.0^42,47.0^46,51]nonahexaconta-1(69),2,4,19,21,23,25,27,42,44,46,48,50,65,67-pentadecaene;5,12,19,26-tetrazoniaheptacyclo[24.2.2.2^2,5.2^7,10.2^12,15.2^16,19.2^21,24]tetraconta-1(29),2(40),3,5(39),7,9,12,14,16(34),17,19(33),21(32),22,24(31),26(30),27,35,37-octadecaene;dodecahexafluorophosphate
识别
CAS号	158394-29-7
PubChem	71308249
ChemSpider	26000999
SMILES	c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2c3cccc2OCCOCCOCCOCCOc4cccc5c4cccc5OCCOCCOCCOCCOc6cccc7c6cccc7OCCOCCOCCOCCOc3c1.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.c1cc2ccc1C[n+]3ccc(cc3)-c4cc[n+](cc4)Cc5ccc(cc5)C[n+]6ccc(cc6)-c7cc[n+](cc7)C2.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F
性质
化学式	C228H236F72N12O30P12
摩尔质量	5363.95 g·mol^−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

另见

• 奧林匹克烯
• 名称独特的化学物质列表

參考資料

1. Amabilino, D. B.; Ashton, P. R.; Reder, A. S.; Spencer, N.; Stoddart, J. F. Olympiadane. Angew. Chem. Int. Ed. Engl. 1994, 33 (12): 1286–1290. doi:10.1002/anie.199412861. 
2. Browne, M. W. Chemists Make Rings Of Interlocked Atoms, A Clue to Life's Origin. The New York Times. 30 August 1994 [3 January 2016]. （原始内容于2021-07-11）.