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维基百科

δ-癸内酯

行進 31, 2023

δ-癸内酯，简称DDL，是一种内酯，化学式 C10H18O2。它天然微量存在于水果[1]和奶制品中。[2]它可以从化学和生物来源获得。[3][4]从化学方法获得的方法是2-戊基环戊酮的拜耳－维立格氧化反应；[5]而生物质方法是通过6-戊基-α-吡喃酮的氢化产生。[4] DDL应用于食品、[6]聚合物[7]和农业[8]。

δ-癸内酯
IUPAC名
6-Pentyloxan-2-one
识别
CAS号 705-86-2  
PubChem 12810
ChemSpider 12282
SMILES
ChEBI 87327
性质
化学式 C10H18O2
摩尔质量 170.25 g·mol−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

δ-癸内酯的S-对映异构体很香，而R-对映异构体则是北美豪猪的警告性恶臭的主要成分。[9]

参见

参考资料

  1. ^ Tamura, Hirotoshi; Appel, Markus; Richling, Elke; Schreier, Peter. Authenticity Assessment of γ- and δ-Decalactone from Prunus Fruits by Gas Chromatography Combustion/Pyrolysis Isotope Ratio Mass Spectrometry (GC-C/P-IRMS). Journal of Agricultural and Food Chemistry. 2005, 53 (13): 5397–5401. PMID 15969525. doi:10.1021/jf0503964. 
  2. ^ Karagül-Yüceer, Yonca; Drake, Maryanne; Cadwallader, Keith R. Aroma-Active Components of Nonfat Dry Milk. Journal of Agricultural and Food Chemistry. 2001, 49 (6): 2948–2953. PMID 11409991. doi:10.1021/jf0009854. 
  3. ^ Corma, Avelino; Iborra, Sara; Mifsud, María; Renz, Michael; Susarte, Manuel. A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones: Synthesis of the Flavouringδ-Decalactone Molecule. Advanced Synthesis & Catalysis. 2004, 346 (23): 257–262. doi:10.1002/adsc.200303234. 
  4. ^ 4.0 4.1 Alam, Md. Imteyaz; Khan, Tuhin S.; Haider, M. Ali. Alternate Biobased Route to Produce δ-Decalactone: Elucidating the Role of Solvent and Hydrogen Evolution in Catalytic Transfer Hydrogenation. ACS Sustainable Chemistry & Engineering. 2019, 7 (3): 2894–2898. doi:10.1021/acssuschemeng.8b05014. 
  5. ^ Corma, Avelino; Iborra, Sara; Mifsud, María; Renz, Michael; Susarte, Manuel. A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones: Synthesis of the Flavouring δ-Decalactone Molecule. Advanced Synthesis & Catalysis. 2004, 346 (23): 257–262. doi:10.1002/adsc.200303234. 
  6. ^ The forty-ninth meeting of the Joint FAO/WHO Expert Committee on Food Additives; WHO food additive series 40; WHO: Geneva, 1998
  7. ^ Martello, Mark T.; Burns, Adam; Hillmyer, Marc. Bulk Ring-Opening Transesterification Polymerization of the Renewable δ-Decalactone Using an Organocatalyst. ACS Macro Letters. 2012, 1: 131–135. doi:10.1021/mz200006s. 
  8. ^ Menger, D. J.; Van Loon, J. J. A.; Takken, W. Assessing the efficacy of candidate mosquito repellents against the background of an attractive source that mimics a human host. Medical and Veterinary Entomology. 2014, 28 (4): 407–413. PMID 24797537. S2CID 13106405. doi:10.1111/mve.12061. 
  9. ^ Li, Guang; Roze, Uldis; Locke, David C. Warning Odor of the North American Porcupine(Erethizon dorsatum). Journal of Chemical Ecology. December 1997, 23 (12): 2737–2754. Bibcode:1997JSP....23.2737L. S2CID 36405223. doi:10.1023/A:1022511026529. 

行進 31, 2023
癸内酯, 简称ddl, 是一种内酯, 化学式, c10h18o2, 它天然微量存在于水果, 和奶制品中, 它可以从化学和生物来源获得, 从化学方法获得的方法是2, 戊基环戊酮的拜耳, 维立格氧化反应, 而生物质方法是通过6, 戊基, 吡喃酮的氢化产生, ddl应用于食品, 聚合物, 和农业, iupac名6, pentyloxan, one识别cas号, pubchem, 12810chemspider, 12282smiles, cccccc1cccc, o1chebi, 87327性质化学式, c10h18o2. d 癸内酯 简称DDL 是一种内酯 化学式 C10H18O2 它天然微量存在于水果 1 和奶制品中 2 它可以从化学和生物来源获得 3 4 从化学方法获得的方法是2 戊基环戊酮的拜耳 维立格氧化反应 5 而生物质方法是通过6 戊基 a 吡喃酮的氢化产生 4 DDL应用于食品 6 聚合物 7 和农业 8 d 癸内酯IUPAC名6 Pentyloxan 2 one识别CAS号 705 86 2 PubChem 12810ChemSpider 12282SMILES CCCCCC1CCCC O O1ChEBI 87327性质化学式 C10H18O2摩尔质量 170 25 g mol 1若非注明 所有数据均出自标准状态 25 100 kPa 下 d 癸内酯的S 对映异构体很香 而R 对映异构体则是北美豪猪的警告性恶臭的主要成分 9 参见 编辑g 癸内酯参考资料 编辑 Tamura Hirotoshi Appel Markus Richling Elke Schreier Peter Authenticity Assessment of g and d Decalactone from Prunus Fruits by Gas Chromatography Combustion Pyrolysis Isotope Ratio Mass Spectrometry GC C P IRMS Journal of Agricultural and Food Chemistry 2005 53 13 5397 5401 PMID 15969525 doi 10 1021 jf0503964 Karagul Yuceer Yonca Drake Maryanne Cadwallader Keith R Aroma Active Components of Nonfat Dry Milk Journal of Agricultural and Food Chemistry 2001 49 6 2948 2953 PMID 11409991 doi 10 1021 jf0009854 Corma Avelino Iborra Sara Mifsud Maria Renz Michael Susarte Manuel A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones Synthesis of the Flavouringd Decalactone Molecule Advanced Synthesis amp Catalysis 2004 346 23 257 262 doi 10 1002 adsc 200303234 4 0 4 1 Alam Md Imteyaz Khan Tuhin S Haider M Ali Alternate Biobased Route to Produce d Decalactone Elucidating the Role of Solvent and Hydrogen Evolution in Catalytic Transfer Hydrogenation ACS Sustainable Chemistry amp Engineering 2019 7 3 2894 2898 doi 10 1021 acssuschemeng 8b05014 Corma Avelino Iborra Sara Mifsud Maria Renz Michael Susarte Manuel A New Environmentally Benign Catalytic Process for the Asymmetric Synthesis of Lactones Synthesis of the Flavouring d Decalactone Molecule Advanced Synthesis amp Catalysis 2004 346 23 257 262 doi 10 1002 adsc 200303234 The forty ninth meeting of the Joint FAO WHO Expert Committee on Food Additives WHO food additive series 40 WHO Geneva 1998 Martello Mark T Burns Adam Hillmyer Marc Bulk Ring Opening Transesterification Polymerization of the Renewable d Decalactone Using an Organocatalyst ACS Macro Letters 2012 1 131 135 doi 10 1021 mz200006s Menger D J Van Loon J J A Takken W Assessing the efficacy of candidate mosquito repellents against the background of an attractive source that mimics a human host Medical and Veterinary Entomology 2014 28 4 407 413 PMID 24797537 S2CID 13106405 doi 10 1111 mve 12061 Li Guang Roze Uldis Locke David C Warning Odor of the North American Porcupine Erethizon dorsatum Journal of Chemical Ecology December 1997 23 12 2737 2754 Bibcode 1997JSP 23 2737L S2CID 36405223 doi 10 1023 A 1022511026529 取自 https zh wikipedia org w index php title D 癸内酯 amp oldid 72317406, 维基百科，wiki，书籍，书籍，图书馆，

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