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爆炸性锑

一月 01, 1970

爆炸性锑是锑元素的一种极度活跃的同素异形体。当它受到刮擦，或突然受热时，就会爆炸。[1][2][3][4][5][6]它于1855年首次被描述，[7][8]可通过电解三氯化锑的盐酸溶液制取。[1][2][3][4]爆炸性锑晶体的边界处常常会出现以卤素为主的杂质。当它爆炸时，平均每克爆炸性锑会释放24卡路里的能量。[9]

参考资料 编辑

  1. ^ 1.0 1.1 Allan C. Topp. Studies on Explosive Antimony and Antimony Tetrachloride Solutions. Dalhousie University. 1939 [2016-11-21]. 
  2. ^ 2.0 2.1 N.C. Norman. Chemistry of Arsenic, Antimony and Bismuth. Springer Science & Business Media. 1997: 50 [2016-11-21]. ISBN 9780751403893. Another possible allotrope, known as explosive antimony, has been reported which is produced by electrolysis of antimony chloride, iodide or bromide and is believed to be in a strained amorphous state. 
  3. ^ 3.0 3.1 Otfried Madelung. Semiconductors: Data Handbook. Springer Science & Business Media. 2012: 408 [2016-11-21]. ISBN 9783642188657. Explosive Antimony is only metastable and transforms into metallic antimony during mechanical stress and heating. Explosive Antimony is probably not an allotropic form, but a mixed polymer. 
  4. ^ 4.0 4.1 Egon Wiberg, Nils Wiberg. Inorganic Chemistry. Academic Press. 2001: 758 [2016-11-21]. ISBN 9780123526519. 
  5. ^ Bernard Martel. Chemical Risk Analysis: A Practical Handbook. Butterworth-Heinemann. 2004 [2016-11-21]. ISBN 9780080529042. 
  6. ^ James H. Walton Jr. Suspended changes in Nature. Popular Science. July 1913: 31 [2016-11-21]. We are indebted to the investigations of Professor Cohen for a more striking example of a metastable metal, that of the " explosive " antimony. By passing an electric current through a solution of antimony chloride this metal may be deposited in the form of a thick metallic coating. 
  7. ^ C.C. Coffin, Stuart Johnston. Studies on Explosive Antimony. I. The Microscopy of Polished Surfaces. Proceedings of the Royal Society of London. 1934-10-01. JSTOR 2935608. 
  8. ^ C.C. Coffin. (PDF). Proceedings of the Royal Society of London. 1935-10-15: 47–63 [2016-11-21]. （原始内容 (PDF)存档于2016-09-12）. 
  9. ^ F. M. Aymerich, A. Delunas. On the explosive semiconductor-semimetal transition of antimony. Physica Status Solidi A (Physica Status Solidi). 1975-09-16, 31 (1): 165–170. Bibcode:1975PSSAR..31Q.165A. doi:10.1002/pssa.2210310118. The energy released by this transition, is measured to be 24 cal per gram of amorphous Sb and is shown to be related to a variation of the mass density and of the conductivity behaviour of Sb going from one configuration to the other. A simple theoretical model is outlined which quite satisfactory gives the gross features of the free-energy diagram of the above transition, although more deep investigation is needed to account for the energy balance of it. 

一月 01, 1970
爆炸性锑, 是锑元素的一种极度活跃的同素异形体, 当它受到刮擦, 或突然受热时, 就会爆炸, 它于1855年首次被描述, 可通过电解三氯化锑的盐酸溶液制取, 晶体的边界处常常会出现以卤素为主的杂质, 当它爆炸时, 平均每克会释放24卡路里的能量, 参考资料, 编辑, allan, topp, studies, explosive, antimony, antimony, tetrachloride, solutions, dalhousie, university, 1939, 2016, norman, chem. 爆炸性锑是锑元素的一种极度活跃的同素异形体 当它受到刮擦 或突然受热时 就会爆炸 1 2 3 4 5 6 它于1855年首次被描述 7 8 可通过电解三氯化锑的盐酸溶液制取 1 2 3 4 爆炸性锑晶体的边界处常常会出现以卤素为主的杂质 当它爆炸时 平均每克爆炸性锑会释放24卡路里的能量 9 参考资料 编辑 1 0 1 1 Allan C Topp Studies on Explosive Antimony and Antimony Tetrachloride Solutions Dalhousie University 1939 2016 11 21 2 0 2 1 N C Norman Chemistry of Arsenic Antimony and Bismuth Springer Science amp Business Media 1997 50 2016 11 21 ISBN 9780751403893 Another possible allotrope known as explosive antimony has been reported which is produced by electrolysis of antimony chloride iodide or bromide and is believed to be in a strained amorphous state 3 0 3 1 Otfried Madelung Semiconductors Data Handbook Springer Science amp Business Media 2012 408 2016 11 21 ISBN 9783642188657 Explosive Antimony is only metastable and transforms into metallic antimony during mechanical stress and heating Explosive Antimony is probably not an allotropic form but a mixed polymer 4 0 4 1 Egon Wiberg Nils Wiberg Inorganic Chemistry Academic Press 2001 758 2016 11 21 ISBN 9780123526519 Bernard Martel Chemical Risk Analysis A Practical Handbook Butterworth Heinemann 2004 2016 11 21 ISBN 9780080529042 James H Walton Jr Suspended changes in Nature Popular Science July 1913 31 2016 11 21 We are indebted to the investigations of Professor Cohen for a more striking example of a metastable metal that of the explosive antimony By passing an electric current through a solution of antimony chloride this metal may be deposited in the form of a thick metallic coating C C Coffin Stuart Johnston Studies on Explosive Antimony I The Microscopy of Polished Surfaces Proceedings of the Royal Society of London 1934 10 01 JSTOR 2935608 C C Coffin Studies on Explosive Antimony II Its Structure Electrical Conductivity and Rate of Crystallization PDF Proceedings of the Royal Society of London 1935 10 15 47 63 2016 11 21 原始内容 PDF 存档于2016 09 12 F M Aymerich A Delunas On the explosive semiconductor semimetal transition of antimony Physica Status Solidi A Physica Status Solidi 1975 09 16 31 1 165 170 Bibcode 1975PSSAR 31Q 165A doi 10 1002 pssa 2210310118 The energy released by this transition is measured to be 24 cal per gram of amorphous Sb and is shown to be related to a variation of the mass density and of the conductivity behaviour of Sb going from one configuration to the other A simple theoretical model is outlined which quite satisfactory gives the gross features of the free energy diagram of the above transition although more deep investigation is needed to account for the energy balance of it nbsp 这是一篇爆炸物相关小作品 你可以通过编辑或修订扩充其内容 查论编 取自 https zh wikipedia org w index php title 爆炸性锑 amp oldid 81454456, 维基百科，wiki，书籍，书籍，图书馆，

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